EN ISO 5398-3:2018
(Main)Leather - Chemical determination of chromic oxide content - Part 3: Quantification by atomic absorption spectrometry (ISO 5398-3:2018)
General Information
- Abstract
This document describes a method for the determination of chromium in aqueous solution obtained from leather. This is an analysis for total chromium in leather; it is not compound specific or specific to its oxidation state.
This method describes the determination of chromium by atomic absorption spectrometry and is applicable to leathers which are expected to have chromic oxide contents in excess of 5 mg/kg. Two techniques for the preparation of the solution to be analysed are included. In the case of disputes, the wet oxidation technique is to be used.
- Status
- Published
- Publication Date
- 17-Jul-2018
- Withdrawal Date
- 30-Jan-2019
- Technical Committee
- CEN/TC 289 - Leather
- Drafting Committee
- CEN/TC 289 - Leather
- Current Stage
- 6060 - Definitive text made available (DAV) - Publishing
- Start Date
- 18-Jul-2018
- Completion Date
- 18-Jul-2018
Overview
EN ISO 5398-3:2018 - "Leather - Chemical determination of chromic oxide content - Part 3: Quantification by atomic absorption spectrometry" is a CEN-endorsed ISO test method for measuring total chromium in leather. The standard specifies how to solubilize chromium from leather into an aqueous solution and quantify it using atomic absorption spectrometry (AAS). Results are reported as chromic oxide (Cr2O3) content in mg/kg (based on dry matter). This method applies to leathers expected to contain more than 5 mg/kg chromic oxide.
Key topics and requirements
- Scope: Determination of total chromium in leather; not compound- or oxidation-state-specific.
- Sample handling: Sampling in accordance with ISO 2418 and sample preparation per ISO 4044. Typical test portion: 2 g of prepared leather (weighed to 0.001 g); at least two determinations per sample.
- Preparation techniques: Two procedures for producing the analytical solution:
- Wet oxidation (specified as the reference method in disputes)
- Microwave digestion
- Reagents: Analytical-grade reagents such as nitric acid (70 %), a sulfuric/perchloric acid mix (1:3 v/v), potassium dichromate standard (traceable), and potassium chloride solution for matrix modification.
- Instrumentation: Atomic absorption spectrophotometer with appropriate hollow cathode lamp and nitrous oxide burner (or high-solids N2O burner). Filtration using glass-fiber or membrane filters is specified.
- Quality and reporting: Use grade 3 water per ISO 3696; calculation and expression of results are defined, and the test report must include sampling and method details. Annexes include guidance on volatile matter determination and suitable AAS equipment.
Practical applications
- Routine laboratory testing of finished leather and leather components for chromium content.
- Compliance testing for regulatory, environmental or product-safety requirements where chromium levels must be known.
- Quality control in tanneries and material suppliers to monitor chromium tanning residues.
- Dispute resolution assays (wet oxidation is mandated if results are contested).
Who should use this standard
- Analytical laboratories performing leather chemistry tests.
- Tannery quality-control teams and product compliance departments.
- Certification bodies, regulators and testing services assessing chromium content in leather goods.
- Research organizations studying chromium in leather processing.
Related standards
- ISO 2418 - Sampling locations for leather
- ISO 4044 - Preparation of chemical test samples
- ISO 3696 - Water for laboratory use
- ISO 4684 - Determination of volatile matter
- EN 14602 - Footwear ecological test methods
This standard is part of the ISO 5398 series and is intended for laboratories that require accurate, AAS-based quantification of chromic oxide in leather products.
Relations
- Effective Date
- 01-Aug-2018
- Effective Date
- 25-Aug-2026
- Effective Date
- 09-Feb-2026
- Refers
ISO 2418:2017 - Leather — Chemical, physical and mechanical and fastness tests — Sampling location - Effective Date
- 09-Feb-2026
- Effective Date
- 09-Feb-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Referred By
EN 16419:2014 - Leather - Chamois leather for cleaning purposes - Classification and requirements - Effective Date
- 28-Jan-2026
- Consolidated By
ISO 5398-3:2018 - Leather — Chemical determination of chromic oxide content — Part 3: Quantification by atomic absorption spectrometry - Effective Date
- 12-Feb-2026
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Frequently Asked Questions
EN ISO 5398-3:2018 is a standard published by the European Committee for Standardization (CEN). Its full title is "Leather - Chemical determination of chromic oxide content - Part 3: Quantification by atomic absorption spectrometry (ISO 5398-3:2018)". This standard covers: This document describes a method for the determination of chromium in aqueous solution obtained from leather. This is an analysis for total chromium in leather; it is not compound specific or specific to its oxidation state. This method describes the determination of chromium by atomic absorption spectrometry and is applicable to leathers which are expected to have chromic oxide contents in excess of 5 mg/kg. Two techniques for the preparation of the solution to be analysed are included. In the case of disputes, the wet oxidation technique is to be used.
This document describes a method for the determination of chromium in aqueous solution obtained from leather. This is an analysis for total chromium in leather; it is not compound specific or specific to its oxidation state. This method describes the determination of chromium by atomic absorption spectrometry and is applicable to leathers which are expected to have chromic oxide contents in excess of 5 mg/kg. Two techniques for the preparation of the solution to be analysed are included. In the case of disputes, the wet oxidation technique is to be used.
EN ISO 5398-3:2018 is classified under the following ICS (International Classification for Standards) categories: 59.140.30 - Leather and furs. The ICS classification helps identify the subject area and facilitates finding related standards.
EN ISO 5398-3:2018 has the following relationships with other standards: It is inter standard links to EN ISO 5398-3:2007, ISO 4684:2005, ISO 4044:2017, ISO 2418:2017, ISO 3696:1987, EN 14602:2012, EN 1457-1:2012, EN ISO 21528-2:2017, CEN/TR 15990:2010, CEN/TR 15990:2021, EN 16419:2014, ISO 5398-3:2018. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
EN ISO 5398-3:2018 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
SLOVENSKI STANDARD
01-oktober-2018
1DGRPHãþD
SIST EN ISO 5398-3:2009
8VQMH.HPLMVNRGRORþHYDQMHNURPRYHJDRNVLGDGHO.YDQWLWDWLYQR
GRORþHYDQMH]DWRPVNRDEVRUSFLMVNRVSHNWURPHWULMR,62
Leather - Chemical determination of chromic oxide content - Part 3: Quantification by
atomic absorption spectrometry (ISO 5398-3:2018)
Leder - Chemische Bestimmung des Chromoxidgehalts - Teil 3: Bestimmung durch
Atomabsorptionsspektrometrie (ISO 5398-3:2018)
Cuir - Dosage chimique de l'oxyde de chrome - Partie 3: Quantification par spectrométrie
d'absorption atomique (ISO 5398-3:2018)
Ta slovenski standard je istoveten z: EN ISO 5398-3:2018
ICS:
59.140.30 Usnje in krzno Leather and furs
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN ISO 5398-3
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2018
EUROPÄISCHE NORM
ICS 59.140.30 Supersedes EN ISO 5398-3:2007
English Version
Leather - Chemical determination of chromic oxide content
- Part 3: Quantification by atomic absorption spectrometry
(ISO 5398-3:2018)
Cuir - Dosage chimique de l'oxyde de chrome - Partie 3: Leder - Chemische Bestimmung des Chromoxidgehalts
Quantification par spectrométrie d'absorption - Teil 3: Bestimmung durch
atomique (ISO 5398-3:2018) Atomabsorptionsspektrometrie (ISO 5398-3:2018)
This European Standard was approved by CEN on 8 June 2018.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 5398-3:2018 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
European foreword
This document (EN ISO 5398-3:2018) has been prepared by Technical Committee IULTCS
"International Union of Leather Technologists and Chemists Societies" in collaboration with Technical
Committee CEN/TC 289 “Leather” the secretariat of which is held by UNI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by January 2019, and conflicting national standards shall
be withdrawn at the latest by January 2019.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 5398-3:2007.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 5398-3:2018 has been approved by CEN as EN ISO 5398-3:2018 without any
modification.
INTERNATIONAL ISO
STANDARD 5398-3
IULTCS/IUC 8-3
Second edition
2018-06
Leather — Chemical determination of
chromic oxide content —
Part 3:
Quantification by atomic absorption
spectrometry
Cuir — Dosage chimique de l'oxyde de chrome —
Partie 3: Quantification par spectrométrie d'absorption atomique
Reference numbers
ISO 5398-3:2018(E)
IULTCS/IUC 8-3:2018(E)
©
ISO 2018
ISO 5398-3:2018(E)
IULTCS/IUC 8-3:2018(E)
© ISO 2018
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
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Published in Switzerland
ii © ISO 2018 – All rights reserved
ISO 5398-3:2018(E)
IULTCS/IUC 8-3:2018(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Sampling and sample preparation . 2
6 Reagents . 2
6.1 Reagents for wet oxidation method . 2
6.2 Reagents for atomic absorption spectrometry . 2
7 Apparatus . 2
8 Methods . 3
8.1 Preparation of analytical solution . 3
8.1.1 Wet oxidation method . 3
8.1.2 Microwave digestion method . 3
8.2 Measurement of the aqueous solution . 3
8.2.1 General. 3
8.2.2 Preparation of calibration graph . 3
8.2.3 Analysis of the test solution . 3
9 Calculation and expression of results . 4
10 Test report . 4
Annex A (informative) Determination of water and other volatile matter . 5
Annex B (informative) Suitable atomic absorption spectrometry (AAS) equipment .6
ISO 5398-3:2018(E)
IULTCS/IUC 8-3:2018(E)
Foreword
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This document was prepared by the Chemical Tests Commission of the International Union of Leather
Technologists and Chemists Societies (IUC Commission, IULTCS) in collaboration with the European
Committee for Standardization (CEN) Technical Committee CEN/TC 289, Leather, the secretariat of
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