prEN ISO 11495

SLOVENSKI STANDARD
01-oktober-2026
Nakit in plemenite kovine - Določanje paladija - Metoda ICP-OES z uporabo
notranjega standardnega elementa (ISO/DIS 11495:2026)
Jewellery and precious metals - Determination of palladium - ICP-OES method using an
internal standard element (ISO/DIS 11495:2026)
Schmuck und Edelmetalle - Bestimmung von Palladium - ICP-OES Verfahren unter
Verwendung eines internen Standardelements (ISO/DIS 11495:2026)
Joaillerie, bijouterie et métaux précieux - Dosage du palladium - Méthode par ICP-OES
utilisant un étalon interne (ISO/DIS 11495:2026)
Ta slovenski standard je istoveten z: prEN ISO 11495
ICS:
39.060 Nakit Jewellery
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
International
Standard
ISO/DIS 11495
ISO/TC 174
Jewellery and precious metals —
Secretariat: DIN
Determination of palladium —
Voting begins on:
ICP-OES method using an internal
2026-07-28
standard element
Voting terminates on:
2026-10-20
Joaillerie, bijouterie et métaux précieux — Dosage du palladium
— Méthode par ICP-OES utilisant un étalon interne
ICS: 39.060
THIS DOCUMENT IS A DRAFT CIRCULATED
FOR COMMENTS AND APPROVAL. IT
IS THEREFORE SUBJECT TO CHANGE
AND MAY NOT BE REFERRED TO AS AN
INTERNATIONAL STANDARD UNTIL
PUBLISHED AS SUCH.
This document has not been edited by the ISO Central Secretariat.
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Reference number
ISO/DIS 11495:2026(en)
DRAFT
ISO/DIS 11495:2026(en)
International
Standard
ISO/DIS 11495
ISO/TC 174
Jewellery and precious metals —
Secretariat: DIN
Determination of palladium —
Voting begins on:
ICP-OES method using an internal
standard element
Voting terminates on:
Joaillerie, bijouterie et métaux précieux — Dosage du palladium
— Méthode par ICP-OES utilisant un étalon interne
ICS: 39.060
THIS DOCUMENT IS A DRAFT CIRCULATED
FOR COMMENTS AND APPROVAL. IT
IS THEREFORE SUBJECT TO CHANGE
AND MAY NOT BE REFERRED TO AS AN
INTERNATIONAL STANDARD UNTIL
PUBLISHED AS SUCH.
This document has not been edited by the ISO Central Secretariat.
IN ADDITION TO THEIR EVALUATION AS
BEING ACCEPTABLE FOR INDUSTRIAL,
© ISO 2026
TECHNOLOGICAL, COMMERCIAL AND
USER PURPOSES, DRAFT INTERNATIONAL
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
STANDARDS MAY ON OCCASION HAVE TO
ISO/CEN PARALLEL PROCESSING
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BE CONSIDERED IN THE LIGHT OF THEIR
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Published in Switzerland Reference number
ISO/DIS 11495:2026(en)
ii
ISO/DIS 11495:2026(en)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Reagents . 2
6 Apparatus . 3
7 Sampling . 3
8 Procedure . 3
8.1 Internal standard solution .3
8.2 Calibration solutions .3
8.3 Sample solutions .4
8.3.1 Preparation of the palladium alloy solution containing ruthenium, iridium or
tungsten .4
8.4 Measurement .4
9 Calculation and expression of results . 5
9.1 Calculation .5
9.2 Repeatability .6
10 Test report . 7
Annex A (informative) Technical background for ICP -OES (inductively coupled argon plasma
optical emission spectrometer) . . 8
Annex B (informative) Interlaboratory testing . 9
Bibliography .10

iii
ISO/DIS 11495:2026(en)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types
of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent
rights identified during the development of the document will be in the Introduction and/or on the ISO list of
patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and expressions
related to conformity assessment, as well as information about ISO's adherence to the World Trade
Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 174, Jewellery and precious metals in
collaboration with the European Committee for Standardization (CEN) Technical Committee CEN/TC 410,
Jewellery and precious metals in accordance with the Agreement on technical cooperation between ISO and
CEN (Vienna Agreement).
This third edition cancels and replaces the second edition (ISO 11495:2014), which has been technically
revised. The main changes compared to the previous edition are as follows:
a) the definition of bracketing in Clause 3 has been removed;
b) the recommended lines in Clause 4 have been removed;
c) reagents and the requirements about internal standard element have been updated;
d) the preparation of the internal standard solution in 8.1 has been changed;
e) the list of standards to be prepared and precisions about qualification of them by linearity as well as
way to choose the low and high standards in 8.2 have been changed;
f) the way of preparation by aliquots for both standard and sample solutions in 8.2 and 8.3 has been
removed;
g) the preparation of both standard and sample solutions in 8.2 and 8.3 has been changed;
h) the definition of bracketing and recommended lines in 8.4 has been added;
i) the formulae in 9.1 have been adapted after having removed the way of preparation by aliquots;
j) the emission line as information to be mentioned in the test report in Clause 10 has been removed;
k) the document has been editorially revised.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.

iv
DRAFT International Standard ISO/DIS 11495:2026(en)
Jewellery and precious metals — Determination of palladium
— ICP-OES method using an internal standard element
1 Scope
This document specifies an analytical method for the determination of palladium on a material considered
homogeneous. The palladium content of the samples lies preferably between 50 ‰ (parts per thousand)
and 990 ‰ (parts per thousand). Fineness above 990,0 ‰ can be determined using a spectroscopy method
by difference ISO 15093.
NOTE Lower contents of palladium can be analysed referring to this method.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content constitutes
requirements of this document. For dated references, only the edition cited applies. For undated references,
the latest edition of the referenced document (including any amendments) applies.
ISO 11596, Jewellery and precious metals — Sampling of precious metals and precious metal alloys
ISO 15093, Jewellery and precious metals — Determination of high purity gold, platinum and palladium —
Difference method using ICP-OES
ISO 19376-1, Jewellery and precious metals — Vocabulary — Part 1: Precious metals and units
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
3.1
calibration solution
solution used to calibrate the instrument, prepared from stock solution or solution prepared with certified
reference material by adding acid, buffer, reference elements and salt as needed
3.2
bracketing
analytical method consisting of bracketing the measured emission line intensity of the sample between two
measurements made on calibration solutions of neighbouring concentrations within the optimum working
range
Note 1 to entry: Running of standards and samples in the following sequence: low standard – sample – high standard –
sample – low standard – sample – high standard …
[SOURCE: ISO 19376-1, 3.3.7]
3.3
laboratory sample
sample intended for laboratory inspection or testing

ISO/DIS 11495:2026(en)
3.4
test portion
portion of material, resulting from the laboratory sample by means of an appropriate method of sample
pretreatment, and having the size (volume/mass) necessary for the desired testing or analysis
[SOURCE: ISO 19376-1, 3.6.7, identical]
3.5
test sample solution
solution prepared after extraction or digestion of the test sample according to appropriate specification
3.6
internal standard
compound added to a sample in a fixed amount that has similar properties to the target analyte used to
correct for instrument drift and matrix interference
[SOURCE: ISO 19376-1, 3.3.8, identical]
3.7
linearity
straight-line relationship between the mean result of measurement and the quantity (concentration) of the
analyte
3.8
linear calibration curve
expression of the relation between indication and corresponding measured quantity value
4 Principle
At least two accurately weighed samples are individually dissolved in aqua regia and made up to an exactly
weighed mass. These sample solutions are mixed with the internal standard and made up to the standard
measuring volume.
Using ICP-OES, the palladium content of the sample solution is measured by comparison of the ratio
intensities of the spectral emission of palladium and appropriate internal standard line(s) with the ratios for
solutions containing known masses of palladium and internal standard using the bracketing method.
Minor modifications are required when the alloy contains ruthenium, rhodium, iridium, or tungsten.
5 Reagents
During the analysis, unless otherwise stated, use only reagents of recognised analytical grade and only
distilled water or water of equi
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