SIST EN 12916:2019/oprA1:2021
(Amendment)Petroleum products - Determination of aromatic hydrocarbon types in middle distillates - High performance liquid chromatography method with refractive index detection
Petroleum products - Determination of aromatic hydrocarbon types in middle distillates - High performance liquid chromatography method with refractive index detection
This document specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels, paraffinic diesel fuels and petroleum distillates.
This document defines two procedures, A and B.
Procedure A is applicable to diesel fuels that may contain fatty acid methyl esters (FAME) up to 30 % (V/V) (as in [1], [2] or [3]) and petroleum distillates in the boiling range from 150 °C to 400 °C (as in [4].
Procedure B is applicable to paraffinic diesel fuels with up to 7 % (V/V) FAME. This procedure does not contain a dilution of the sample in order to determine the low levels of aromatic components in these fuels.
The polycyclic aromatic hydrocarbons content is calculated from the sum of di-aromatic and tri+-aromatic hydrocarbons and the total content of aromatic compounds is calculated from the sum of the individual aromatic hydrocarbon types.
Compounds containing sulfur, nitrogen and oxygen can interfere in the determination; mono-alkenes do not interfere, but conjugated di-alkenes and poly-alkenes, if present, can do so.
NOTE 1 For the purpose of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction, µ, and the volume fraction, φ, of a material respectively.
NOTE 2 By convention, the aromatic hydrocarbon types are defined on the basis of their elution characteristics from the specified liquid chromatography column relative to model aromatic compounds. Their quantification is performed using an external calibration with a single aromatic compound for each of them, which may or may not be representative of the aromatics present in the sample. Alternative techniques and test methods may classify and quantify individual aromatic hydrocarbon types differently.
NOTE 3 Backflush is part of laboratory-internal maintenance.
WARNING - The use of this standard can involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this standard to take appropriate measures to ensure the safety and health of personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this purpose.
Mineralölerzeugnisse - Bestimmung von aromatischen Kohlenwasserstoffgruppen in Mitteldestillaten - Hochleistungsflüssigkeitschromatographie-Verfahren mit Brechzahl-Detektion
Produits pétroliers - Détermination des familles d'hydrocarbures aromatiques dans les distillats moyens - Méthode par chromatographie liquide à haute performance avec détection par réfractométrie différentielle
Naftni proizvodi - Določevanje aromatskih ogljikovodikov v srednjih destilatih - Metoda tekočinske kromatografije visoke ločljivosti z detekcijo lomnega količnika
General Information
- Status
- Not Published
- Public Enquiry End Date
- 02-Jan-2022
- Technical Committee
- NAD - Petroleum products, lubricants and related products
- Current Stage
- 98 - Abandoned project (Adopted Project)
- Start Date
- 19-Aug-2022
- Due Date
- 24-Aug-2022
- Completion Date
- 19-Aug-2022
Relations
- Effective Date
- 01-Oct-2022
- Effective Date
- 01-Dec-2021
Overview
SIST EN 12916:2019/oprA1:2021 defines a standardized method for determining aromatic hydrocarbon types in middle distillates, including diesel fuels and paraffinic diesel fuels. Utilizing high performance liquid chromatography (HPLC) with refractive index detection, this standard specifies procedures for quantifying mono-aromatic, di-aromatic, and tri+-aromatic hydrocarbons. It is essential for laboratories, refineries, and other stakeholders working with petroleum products to ensure product quality, comply with regulations, and monitor environmental impact.
This standard is maintained by SIST as a modification of EN 12916:2019, reflecting updated precision ranges and clarifications for analytical procedures.
Key Topics
- Aromatic Hydrocarbon Quantification: The standard details methodologies for separating and measuring aromatic compounds in fuel samples, offering reliable quantification of mono-, di-, and tri+-aromatics.
- Analytical Procedures: Two procedures are defined:
- Procedure A: Applicable to diesel fuels with up to 30% (V/V) Fatty Acid Methyl Esters (FAME) and relevant petroleum distillates.
- Procedure B: Tailored for paraffinic diesel fuels with up to 7% (V/V) FAME, focusing on low levels of aromatic content without sample dilution.
- Calculation and Classification: Aromatic content is calculated based on sum totals of defined groups; the classification relies on chromatographic elution characteristics.
- Interference Considerations: The standard highlights possible analytical interferences, including compounds containing sulfur, nitrogen, or oxygen, and poly-alkenes.
Applications
SIST EN 12916:2019/oprA1:2021 is widely applicable across the petroleum sector, including:
- Quality Control Laboratories: Ensures consistency and specification compliance in commercial diesel and paraffinic fuels.
- Refineries and Fuel Producers: Supports product development and process optimization by providing a trusted method for aromatic quantification.
- Regulatory Affairs: Assists organizations in demonstrating compliance with international and national fuel standards regarding aromatic hydrocarbon limits.
- Environmental Monitoring: Essential for monitoring fuel composition and supporting environmental reporting requirements.
- Research and Development: Facilitates the study of fuel additives and their influence on aromatic profiles, supporting innovation and improved fuel formulations.
Related Standards
For comprehensive petroleum product testing and analysis, consider the following standards:
- EN 12916:2019: The foundational European standard for aromatic hydrocarbon determination in middle distillates.
- EN ISO 4259: Guidelines for evaluating precision and bias in test method results (note: has been withdrawn but referenced for precision calculations).
- EN 590: Specification standards for automotive diesel fuels.
- EN 228: Specifications for unleaded petrol.
- ISO 13739: General guidelines for physical and chemical analysis of fuels.
SIST EN 12916:2019/oprA1:2021 is important for ensuring accuracy in fuel analysis, quality assurance, and compliance with regulatory requirements. By applying this method, organizations can confidently evaluate the aromatic content of petroleum middle distillates using advanced chromatographic techniques.
For safety, always follow relevant health and safety regulations when conducting fuel analyses as outlined in the standard.
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Frequently Asked Questions
SIST EN 12916:2019/oprA1:2021 is a draft published by the Slovenian Institute for Standardization (SIST). Its full title is "Petroleum products - Determination of aromatic hydrocarbon types in middle distillates - High performance liquid chromatography method with refractive index detection". This standard covers: This document specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels, paraffinic diesel fuels and petroleum distillates. This document defines two procedures, A and B. Procedure A is applicable to diesel fuels that may contain fatty acid methyl esters (FAME) up to 30 % (V/V) (as in [1], [2] or [3]) and petroleum distillates in the boiling range from 150 °C to 400 °C (as in [4]. Procedure B is applicable to paraffinic diesel fuels with up to 7 % (V/V) FAME. This procedure does not contain a dilution of the sample in order to determine the low levels of aromatic components in these fuels. The polycyclic aromatic hydrocarbons content is calculated from the sum of di-aromatic and tri+-aromatic hydrocarbons and the total content of aromatic compounds is calculated from the sum of the individual aromatic hydrocarbon types. Compounds containing sulfur, nitrogen and oxygen can interfere in the determination; mono-alkenes do not interfere, but conjugated di-alkenes and poly-alkenes, if present, can do so. NOTE 1 For the purpose of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction, µ, and the volume fraction, φ, of a material respectively. NOTE 2 By convention, the aromatic hydrocarbon types are defined on the basis of their elution characteristics from the specified liquid chromatography column relative to model aromatic compounds. Their quantification is performed using an external calibration with a single aromatic compound for each of them, which may or may not be representative of the aromatics present in the sample. Alternative techniques and test methods may classify and quantify individual aromatic hydrocarbon types differently. NOTE 3 Backflush is part of laboratory-internal maintenance. WARNING - The use of this standard can involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this standard to take appropriate measures to ensure the safety and health of personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this purpose.
This document specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels, paraffinic diesel fuels and petroleum distillates. This document defines two procedures, A and B. Procedure A is applicable to diesel fuels that may contain fatty acid methyl esters (FAME) up to 30 % (V/V) (as in [1], [2] or [3]) and petroleum distillates in the boiling range from 150 °C to 400 °C (as in [4]. Procedure B is applicable to paraffinic diesel fuels with up to 7 % (V/V) FAME. This procedure does not contain a dilution of the sample in order to determine the low levels of aromatic components in these fuels. The polycyclic aromatic hydrocarbons content is calculated from the sum of di-aromatic and tri+-aromatic hydrocarbons and the total content of aromatic compounds is calculated from the sum of the individual aromatic hydrocarbon types. Compounds containing sulfur, nitrogen and oxygen can interfere in the determination; mono-alkenes do not interfere, but conjugated di-alkenes and poly-alkenes, if present, can do so. NOTE 1 For the purpose of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction, µ, and the volume fraction, φ, of a material respectively. NOTE 2 By convention, the aromatic hydrocarbon types are defined on the basis of their elution characteristics from the specified liquid chromatography column relative to model aromatic compounds. Their quantification is performed using an external calibration with a single aromatic compound for each of them, which may or may not be representative of the aromatics present in the sample. Alternative techniques and test methods may classify and quantify individual aromatic hydrocarbon types differently. NOTE 3 Backflush is part of laboratory-internal maintenance. WARNING - The use of this standard can involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this standard to take appropriate measures to ensure the safety and health of personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this purpose.
SIST EN 12916:2019/oprA1:2021 is classified under the following ICS (International Classification for Standards) categories: 71.040.50 - Physicochemical methods of analysis; 75.080 - Petroleum products in general. The ICS classification helps identify the subject area and facilitates finding related standards.
SIST EN 12916:2019/oprA1:2021 has the following relationships with other standards: It is inter standard links to SIST EN 12916:2019+A1:2022, SIST EN 12916:2019. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
SIST EN 12916:2019/oprA1:2021 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
SLOVENSKI STANDARD
01-december-2021
Naftni proizvodi - Določevanje aromatskih ogljikovodikov v srednjih destilatih -
Metoda tekočinske kromatografije visoke ločljivosti z detekcijo lomnega količnika
Petroleum products - Determination of aromatic hydrocarbon types in middle distillates -
High performance liquid chromatography method with refractive index detection
Mineralölerzeugnisse - Bestimmung von aromatischen Kohlenwasserstoffgruppen in
Mitteldestillaten - Hochleistungsflüssigkeitschromatographie-Verfahren mit Brechzahl-
Detektion
Produits pétroliers - Détermination des familles d'hydrocarbures aromatiques dans les
distillats moyens - Méthode par chromatographie liquide à haute performance avec
détection par réfractométrie différentielle
Ta slovenski standard je istoveten z: EN 12916:2019/prA1
ICS:
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
75.080 Naftni proizvodi na splošno Petroleum products in
general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
DRAFT
EUROPEAN STANDARD
EN 12916:2019
NORME EUROPÉENNE
EUROPÄISCHE NORM
prA1
December 2021
ICS
English Version
Petroleum products - Determination of aromatic
hydrocarbon types in middle distillates - High
performance liquid chromatography method with
refractive index detection
Produits pétroliers - Détermination des familles Mineralölerzeugnisse - Bestimmung von aromatischen
d'hydrocarbures aromatiques dans les distillats Kohlenwasserstoffgruppen in Mitteldestillaten -
moyens - Méthode par chromatographie liquide à Hochleistungsflüssigkeitschromatographie-Verfahren
haute performance avec détection par réfractométrie mit Brechzahl-Detektion
différentielle
This draft amendment is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee CEN/TC 19.
This draft amendment A1, if approved, will modify the European Standard EN 12916:2019. If this draft becomes an amendment,
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for inclusion of
this amendment into the relevant national standard without any alteration.
This draft amendment was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, N
...



