Liquid petroleum products - Oxygenates blending in line with actual EN 228 requirements

This Technical Report provides information to the blender on all the effects when blending oxygenates and alcohols in order to fulfil legal limitations put in place through the revised Fuels Quality Directive and in order to remain in spec for EN 228 unleaded petrol requirements.
This Technical Report is published as background information.
NOTE   For the purposes of this Technical Report, the terms % (m/m) and % (V/V) are used to represent respectively the mass fraction, µ, and the volume fraction.

Flüssige Mineralölerzeugnisse - Zumischung von sauerstoffhaltigen Verbindungen entsprechend den bestehenden Anforderungen nach EN 228

Produits pétroliers liquides - Oxygenates blending par exigences actuelles d'EN 228

Tekoči naftni proizvodi - Linijsko namešavanje oksigenatov skladno z zahtevami EN 228

To tehnično poročilo izvajalcem mešanja podaja informacije v zvezi z vsemi učinki namešavanja oksigenatov in alkoholov za izpolnjevanje zakonskih omejitev, ki jih je uvedla revidirana direktiva o kakovosti goriv, ter za ohranjanje skladnosti z zahtevami standarda EN 228 v zvezi z neosvinčenim motornim bencinom. To tehnično poročilo je objavljeno kot dodatna informacija.

General Information

Status
Published
Publication Date
26-Nov-2012
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
07-Nov-2012
Due Date
12-Jan-2013
Completion Date
27-Nov-2012

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Technical report

SIST-TP CEN/TR 16435:2013

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Overview

SIST-TP CEN/TR 16435:2013 is a Technical Report that provides essential background guidance for the blending of oxygenates and alcohols in liquid petroleum products, specifically in line with the current requirements of EN 228 for unleaded petrol. Prepared by the Slovenian Institute for Standardization (SIST), the document addresses the challenges blenders face in meeting legal limitations set out in the revised Fuels Quality Directive and maintaining compliance with EN 228 standards for petrol fuels.

Oxygenates, such as ethanol and ethers, are commonly blended into petrol to meet regulatory and environmental requirements, notably concerning oxygen content and related emissions. This report aids stakeholders by detailing relevant blend examples, properties of oxygenates, and the relationship between mass and volume fractions (% m/m and % V/V), supporting both regulatory compliance and product quality targets in the automotive fuels sector.

Key Topics

  • Legal and Regulatory Framework:

    • Focuses on the implications of the revised Fuels Quality Directive (including references to Directive 2009/30/EC and 2011/63/EU) and their requirements for oxygenate use in petrol blending.
    • Outlines how to stay within the prescribed limits for oxygenates and oxygen content in accordance with EN 228:2012.
  • Characteristics of Oxygenates:

    • Provides comparative data on various oxygenates (e.g., methanol, ethanol, isopropyl alcohol, ETBE) including density, molecular weight, and typical oxygen content.
    • Discusses the impact of blending on fuel properties, emphasizing how composition and purity influence final petrol characteristics.
  • Blending Guidelines:

    • Examines the conversion calculation between mass fraction (% m/m) and volume fraction (% V/V) of different components, addressing variations in density and potential non-linear interactions within blends.
    • Features several example blends (e.g., E5 and E10 grades) to illustrate practical approaches for meeting the oxygen content specifications in line with EN 228.
  • Reference Data and Calculations:

    • Summarizes key data from EN 228:2012, covering typical oxygenates allowed for use and how to calculate blending ratios.

Applications

  • Fuel Production and Blending:

    • Guides fuel blenders and refiners in selecting, proportioning, and blending oxygenates to satisfy both legal and quality requirements for unleaded petrol.
    • Useful in ensuring that final fuel products remain within the oxygen content limits set by EN 228 and European fuel quality directives.
  • Quality Assurance:

    • Supports laboratory and quality control staff in verifying that blending operations comply with regulatory standards on oxygenate content.
    • Assists compliance teams in adopting best practices for measurement and reporting aligned with legislative demands.
  • Technical Training and Reference:

    • Serves as a reference tool for training personnel involved in fuel formulation and regulatory compliance.
    • Provides foundational data for technical professionals working with petrol quality specification and fuel innovation.

Related Standards

  • EN 228:2012 - Automotive fuels – Unleaded petrol – Requirements and test methods. The key European standard detailing specifications for unleaded petrol, directly referenced in this technical report.
  • Directive 2009/30/EC - European regulation addressing fuel specifications and greenhouse gas emission reduction requirements.
  • Directive 2011/63/EU - Amendment to Directive 98/70/EC adapting standards to technical progress.
  • Alternative Fuel Technology Series and other technical handbooks cited for detailed fuel and oxygenate properties.

Adhering to SIST-TP CEN/TR 16435:2013 ensures effective, compliant blending practices for liquid petroleum products, supporting clean fuel initiatives and helping organizations meet stringent European fuel quality regulations.

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Technical report

SIST-TP CEN/TR 16435:2013

English language (7 pages)
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Frequently Asked Questions

SIST-TP CEN/TR 16435:2013 is a technical report published by the Slovenian Institute for Standardization (SIST). Its full title is "Liquid petroleum products - Oxygenates blending in line with actual EN 228 requirements". This standard covers: This Technical Report provides information to the blender on all the effects when blending oxygenates and alcohols in order to fulfil legal limitations put in place through the revised Fuels Quality Directive and in order to remain in spec for EN 228 unleaded petrol requirements. This Technical Report is published as background information. NOTE For the purposes of this Technical Report, the terms % (m/m) and % (V/V) are used to represent respectively the mass fraction, µ, and the volume fraction.

This Technical Report provides information to the blender on all the effects when blending oxygenates and alcohols in order to fulfil legal limitations put in place through the revised Fuels Quality Directive and in order to remain in spec for EN 228 unleaded petrol requirements. This Technical Report is published as background information. NOTE For the purposes of this Technical Report, the terms % (m/m) and % (V/V) are used to represent respectively the mass fraction, µ, and the volume fraction.

SIST-TP CEN/TR 16435:2013 is classified under the following ICS (International Classification for Standards) categories: 75.160.20 - Liquid fuels. The ICS classification helps identify the subject area and facilitates finding related standards.

SIST-TP CEN/TR 16435:2013 is associated with the following European legislation: EU Directives/Regulations: 98/70/EC. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.

SIST-TP CEN/TR 16435:2013 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


SLOVENSKI STANDARD
01-januar-2013
7HNRþLQDIWQLSURL]YRGL/LQLMVNRQDPHãDYDQMHRNVLJHQDWRYVNODGQR]]DKWHYDPL
(1
Liquid petroleum products - Oxygenates blending in line with actual EN 228 requirements
Flüssige Mineralölerzeugnisse - Zumischung von sauerstoffhaltigen Verbindungen
entsprechend den bestehenden Anforderungen nach EN 228
Produits pétroliers liquides - Oxygenates blending par exigences actuelles d'EN 228
Ta slovenski standard je istoveten z: CEN/TR 16435:2012
ICS:
75.160.20 7HNRþDJRULYD Liquid fuels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

TECHNICAL REPORT
CEN/TR 16435
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
October 2012
ICS 91.100.01
English Version
Liquid petroleum products - Oxygenates blending in line with
actual EN 228 requirements
Produits pétroliers liquides - Oxygenates blending par Flüssige Mineralölerzeugnisse - Zumischung von
exigences actuelles d'EN 228 sauerstoffhaltigen Verbindungen entsprechend den
bestehenden Anforderungen nach EN 228

This Technical Report was approved by CEN on 25 September 2012. It has been drawn up by the Technical Committee CEN/TC 19.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2012 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 16435:2012: E
worldwide for CEN national Members.

Contents Page
Foreword .3
1 Scope .4
2 Background .4
3 General issues .4
4 Reference data .4
5 Blend examples.5
Bibliography .7

Foreword
This document (CEN/TR 16435:2012) has been prepared by Technical Committee CEN/TC 19 “Gaseous and
liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat of
which is held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
1 Scope
This Technical Report provides information to the blender on all the effects when blending oxygenates and
alcohols in order to fulfil legal limitations put in place through the revised Fuels Quality Directive and in order
to remain in line with EN 228 unleaded petrol requirements.
This Technical Report is published as background information.
NOTE For the purposes of this Technical Report, the terms “% (m/m)” and “% (V/V)” are used to represent
respectively the mass fraction, µ, and the volume fraction, φ.
2 Background
The purpose of this Technical Report is to provide guidance when blending oxygenates while meeting the
requirements of EN 228:2012 [3] for both oxygenates and oxygen content as listed in Table 1 and Table 2 of
that European Standard.
Selected properties of some commonly used oxygenates and examples of six oxygenated blends are reported
to demonstrate the relationship between the concentration of oxygenated blending components and oxygen
content.
The data given in this document are based on the properties of pure chemical products. If impurities, by-
products or unreacted feedstocks are present in the oxygenates, these data may differ slightly from those for
commercial oxygenates.
3 General issues
The relationship between oxygenate contents expressed in % (m/m) and %(V/V) depends on the density of
the individual componen
...