CEN/TR 10317:2014

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European certified reference materials (EURONORM-CRMs) for the determination of the
chemical composition of iron and steel products prepared under the auspices of the
European Committee for Iron and Steel Standardization (ECISS)
Europäische zertifizierte Referenzmaterialien (EURONORM-ZRMs) für die Bestimmung
der chemischen Zusammensetzung von Eisen- und Stahlerzeugnissen, hergestellt unter
der Schirmherrschaft des Europäischen Komitees für Eisen- und Stahlnormung (ECISS)
Matériaux de référence certifiés européens (EURONORM-MRC) destinés à la
détermination de la composition chimique des produits en acier et en fonte préparés
sous les auspices du comité européen de normalisation du fer et de l'acier (ECISS)
Ta slovenski standard je istoveten z: CEN/TR 10317:2014
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
77.140.01 Železni in jekleni izdelki na Iron and steel products in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

TECHNICAL REPORT
CEN/TR 10317
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
November 2014
ICS 71.040.30; 77.150.10 Supersedes CEN/TR 10317:2013
English Version
European certified reference materials (EURONORM-CRMs) for
the determination of the chemical composition of iron and steel
products prepared under the auspices of the European
Committee for Iron and Steel Standardization (ECISS)
Matériaux de référence certifiés européens (EURONORM- Europäische zertifizierte Referenzmaterialien
MRC) destinés à la détermination de la composition (EURONORM-ZRMs) für die Bestimmung der chemischen
chimique des produits en acier et en fonte préparés sous Zusammensetzung von Eisen- und Stahlerzeugnissen,
les auspices du comité européen de normalisation du fer et hergestellt unter der Schirmherrschaft des Europäischen
de l'acier (ECISS) Komitees für Eisen- und Stahlnormung (ECISS)

This Technical Report was approved by CEN on 10 May 2014. It has been drawn up by the Technical Committee ECISS/TC 102.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 10317:2014 E
worldwide for CEN national Members.

Contents Page
Foreword .3
Introduction .4
1 Scope .5
2 Classification of EURONORM-CRMs .5
3 Preparation of the samples .6
3.1 EURONORM-CRMs of cast and wrought materials .6
3.2 EURONORM-CRMs of non-metallic materials .6
4 Certification .7
4.1 Main rules .7
4.2 Main content of the certificates .7
5 Sample presentation .9
6 Distribution of EURONORM-CRMs .9
7 Details of current EURONORM-CRMs . 10
Bibliography . 11

Foreword
This document (CEN/TR 10317:2014) has been prepared by Technical Committee ECISS/TC 102 “Methods
of chemical analysis for iron and steel”, the secretariat of which is held by SIS.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN/TR 10317:2013.
In comparison with the previous edition, CEN/TR 10317:2013, significant technical changes were made to the
introduction and Clause 5 following the withdrawal of Bureau of Analysed Samples Limited from the
Euronorm-CRM Producers’ Group in 2013.
Introduction
ln accordance with the definition in ISO Guide 30, Amendment 1:2008, a Certified Reference Material (CRM)
as described in this CEN Technical Report is a “reference material characterized by a metrologically valid
procedure for one or more specified properties, accompanied by a certificate that provides the value of the
specified property, its associated uncertainty, and a statement of metrological traceability”. Furthermore, it is
accompanied by a certificate issued by the producing organization on behalf of the Co-ordinating Committee
(COCOR) of ECISS after approval by the participating laboratories and all the producing organizations:
a) France:
1) ArcelorMittal Maizières Research SA (AMMZ) [former Institut de Recherches de la Sidérurgie
Française (IRSID)],
2) Centre Technique des Industries de la Fonderie (CTIF);
b) Germany: Iron and Steel CRM Working Group (AGZRM) comprising:
1) BAM Bundesanstalt für Materialforschung und -prüfung,
2) Max-Planck-Institut für Eisenforschung (MPI),
3) Stahlinstitut VDEh;
c) Nordic Countries: Nordic CRM Working Group, (NCRMWG) comprising:
1) Swerea KIMAB [former Swedish Institute for Metals Research (SIMR)],
2) Jernkontoret.
NOTE Bureau of Analysed Samples Ltd (BAS) - United Kingdom – was a member of the EURONORM-CRM
Producer's Group from 1975 until 2013.
Since 1968, EURONORM-CRMs have been analysed by laboratories in most countries in the European Union
(EU) or former European Community (EC).
Pending their eventual replacement by EURONORM-CRMs, a number of former national CRMs prepared,
analysed and certified by laboratories in Germany, France and the United Kingdom respectively, were
accepted as EURONORM-CRMs after their accuracy had been checked by other European laboratories. This
procedure ceased in 1990.
1 Scope
This Technical Report describes the classification, method of sample preparation, certification main rules and
certificate content of the EURONORM-CRMs.
It also details the sample presentation of the various producers' organizations and the distributing sources.
2 Classification of EURONORM-CRMs
EURONORM-CRMs, prepared under the auspices of ECISS, are classified into two main groups:
— cast and wrought materials: irons, steels, special alloys and ferro-alloys;
— non-metallic materials: raw materials (ores, concentrates, additives and refractories) and by-products
(slags, dusts and similar materials).
Besides this first generic classification, EURONORM-CRMs are grouped into the following categories:
a) From 001 to 099 – high purity irons and unalloyed steels
Normally no element has a content (mass fraction) greater than the limit values in the following list:
1) silicon, limit value 1,0 %;
2) manganese, limit value 1,5 %;
3) chromium and nickel, limit value for each 0,5 %;
4) cobalt, copper and tungsten, limit value for each 0,3 %;
5) other elements, limit value for each 0,1 %;
6) boron, carbon, phosphorus, lead and sulphur, no limit value.
b) From 101 to 199 – low alloy steels
The content of one or more elements is greater than the limit given for unalloyed steels but none exceeds
5 %. The sum of these alloying elements remains under 10 %.
c) From 201 – 299 – highly alloyed steels
The content of one or more elements is greater than 5 % or the sum of all these alloying elements is at
least 10 %. Nevertheless the iron content will normally be greater than 50 %.
d) From 301 to 399 - special alloys
The iron content is less than 50 %.
e) From 401 to 499 – pig irons and cast irons
f) From 501 to 599 – ferro-alloys
g) From 601 to 699 – ores, concentrates, sinters and miscellaneous materials
h) From 701 to 799 – additives and refractories
i) From 801 to 899 – by-products, such as slags, dusts and similar materials
The expression “-1” after a CRM number refers to the first issue of this CRM and “-2”, “-3”, etc. refer to
replacement CRMs of generally similar composition, but not to a further bottling of the original CRM.
NOTE This classification is used as a simple and convenient method of differentiating between samples of different
types of materials. It has no other objective and does not replace existing European or International product specifications
for metallic materials.
3 Preparation of the samples
3.1 EURONORM-CRMs of cast and wrought materials
3.1.1 High purity irons, steels and special alloys
The material is obtained as cylindrical, square or rectangular billets or slabs. After the homogeneity has been
verified, it is machined dry (avoi
...