General Information

Abstract

ISO 8502-2:2005 describes a method for the determination of chloride-containing salts that are readily soluble in water and are present on a steel surface. The method is also applicable to previously coated surfaces. It will normally be used in a laboratory using washings sampled from surfaces on site.
ISO 8502-2:2005 is applicable to the determination of salts that have been deposited on the steel surface before, during or after the cleaning operations.
ISO 8502-2:2005 is not applicable to surfaces treated with chromate, nitrite or amine, which are commonly used as inhibitors in the water when wet blast-cleaning. This is because a chromate concentration of 10 mg/l or greater or a nitrite concentration of 20 mg/l or greater in the wash water interferes with the determination of the chloride. Also the amine inhibitors can form a hydroxide boundary layer (not water soluble) over the substrate and prevent the water from contacting the underlying salt for its removal. An iron(III) ion concentration of 10 mg/l also interferes with the determination, but the iron(III) ions are concentrated in the rust deposits, which are removed from the test solution by filtration.

Status
Withdrawn
Publication Date
14-Oct-2005
Withdrawal Date
22-Sep-2026
Current Stage
9960 - Withdrawal effective - Withdrawal
Start Date
08-Feb-2017
Completion Date
23-Sep-2026

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EN ISO 8502-2:2006

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Effective Date
22-Dec-2008
Effective Date
08-Jun-2022
Effective Date
09-Feb-2026
Effective Date
28-Jan-2026
Effective Date
12-Feb-2026

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EN ISO 8502-2:2006

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Frequently Asked Questions

EN ISO 8502-2:2005 is a standard published by the European Committee for Standardization (CEN). Its full title is "Preparation of steel substrates before application of paints and related products - Tests for the assessment of surface cleanliness - Part 2: Laboratory determination of chloride on cleaned surfaces (ISO 8502-2:2005)". This standard covers: ISO 8502-2:2005 describes a method for the determination of chloride-containing salts that are readily soluble in water and are present on a steel surface. The method is also applicable to previously coated surfaces. It will normally be used in a laboratory using washings sampled from surfaces on site. ISO 8502-2:2005 is applicable to the determination of salts that have been deposited on the steel surface before, during or after the cleaning operations. ISO 8502-2:2005 is not applicable to surfaces treated with chromate, nitrite or amine, which are commonly used as inhibitors in the water when wet blast-cleaning. This is because a chromate concentration of 10 mg/l or greater or a nitrite concentration of 20 mg/l or greater in the wash water interferes with the determination of the chloride. Also the amine inhibitors can form a hydroxide boundary layer (not water soluble) over the substrate and prevent the water from contacting the underlying salt for its removal. An iron(III) ion concentration of 10 mg/l also interferes with the determination, but the iron(III) ions are concentrated in the rust deposits, which are removed from the test solution by filtration.

ISO 8502-2:2005 describes a method for the determination of chloride-containing salts that are readily soluble in water and are present on a steel surface. The method is also applicable to previously coated surfaces. It will normally be used in a laboratory using washings sampled from surfaces on site. ISO 8502-2:2005 is applicable to the determination of salts that have been deposited on the steel surface before, during or after the cleaning operations. ISO 8502-2:2005 is not applicable to surfaces treated with chromate, nitrite or amine, which are commonly used as inhibitors in the water when wet blast-cleaning. This is because a chromate concentration of 10 mg/l or greater or a nitrite concentration of 20 mg/l or greater in the wash water interferes with the determination of the chloride. Also the amine inhibitors can form a hydroxide boundary layer (not water soluble) over the substrate and prevent the water from contacting the underlying salt for its removal. An iron(III) ion concentration of 10 mg/l also interferes with the determination, but the iron(III) ions are concentrated in the rust deposits, which are removed from the test solution by filtration.

EN ISO 8502-2:2005 is classified under the following ICS (International Classification for Standards) categories: 25.220.10 - Surface preparation. The ICS classification helps identify the subject area and facilitates finding related standards.

EN ISO 8502-2:2005 has the following relationships with other standards: It is inter standard links to EN ISO 8502-2:1999, EN ISO 8502-2:2017, ISO 3696:1987, CEN/CLC/TR 17602-80-04:2021, ISO 8502-2:2005. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

EN ISO 8502-2:2005 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


SLOVENSKI STANDARD
01-april-2006
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SIST EN ISO 8502-2:1999
3ULSUDYDMHNOHQLKSRGODJSUHGQDQDãDQMHPEDUYLQVRURGQLKL]GHONRY±3UHVNXVL
XJRWDYOMDQMDþLVWRVWLSRGODJH±GHO/DERUDWRULMVNRGRORþHYDQMHNORULGRYQD
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Preparation of steel substrates before application of paints and related products - Tests
for the assessment of surface cleanliness - Part 2: Laboratory determination of chloride
on cleaned surfaces (ISO 8502-2:2005)
Vorbereitung von Stahloberflächen vor dem Auftragen von Beschichtungsstoffen -
Prüfungen zum Beurteilen der Oberflächenreinheit - Teil 2: Laborbestimmung von
Chlorid auf gereinigten Oberflächen (ISO 8502-2:2005)
Préparation des subjectiles d'acier avant application de peintures et de produits
assimilés - Essais pour apprécier la propreté d'une surface - Partie 2: Recherche en
laboratoire des chlorures sur les surfaces nettoyées (ISO 8502-2:2005)
Ta slovenski standard je istoveten z: EN ISO 8502-2:2005
ICS:
25.220.10 Priprava površine Surface preparation
87.020 Postopki za nanašanje Paint coating processes
barvnih premazov
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 8502-2
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2005
ICS 25.220.10 Supersedes EN ISO 8502-2:1999
English Version
Preparation of steel substrates before application of paints and
related products - Tests for the assessment of surface
cleanliness - Part 2: Laboratory determination of chloride on
cleaned surfaces (ISO 8502-2:2005)
Préparation des subjectiles d'acier avant application de Vorbereitung von Stahloberflächen vor dem Auftragen von
peintures et de produits assimilés - Essais pour apprécier Beschichtungsstoffen - Prüfungen zur Beurteilen der
la propreté d'une surface - Partie 2: Recherche en Oberflächenreinheit - Teil 2: Laborbestimmung von Chlorid
laboratoire des chlorures sur les surfaces nettoyées (ISO auf gereinigten Oberflächen (ISO 8502-2:2005)
8502-2:2005)
This European Standard was approved by CEN on 8 August 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 8502-2:2005: E
worldwide for CEN national Members.

Foreword
This document (EN ISO 8502-2:2005) has been prepared by Technical Committee ISO/TC 35
"Paints and varnishes" in collaboration with Technical Committee CEN/TC 139 "Paints and
varnishes", the secretariat of which is held by DIN.

This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by April 2006, and conflicting national
standards shall be withdrawn at the latest by April 2006.

This document supersedes EN ISO 8502-2:1999.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

Endorsement notice
The text of ISO 8502-2:2005 has been approved by CEN as EN ISO 8502-2:2005 without any
modifications.
INTERNATIONAL ISO
STANDARD 8502-2
Second edition
2005-10-15
Corrected version
2006-01-15
Preparation of steel substrates before
application of paints and related
products — Tests for the assessment of
surface cleanliness —
Part 2:
Laboratory determination of chloride on
cleaned surfaces
Préparation des subjectiles d'acier avant application de peintures et de
produits assimilés — Essais pour apprécier la propreté d'une surface —
Partie 2: Recherche en laboratoire des chlorures sur les surfaces
nettoyées
Reference number
ISO 8502-2:2005(E)
©
ISO 2005
ISO 8502-2:2005(E)
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Published in Switzerland
ii © ISO 2005 – All rights reserved

ISO 8502-2:2005(E)
Contents Page
Foreword. iv
Introduction . v
1 Scope . 1
2 Normative references . 1
3 Principle. 2
4 Reagents and materials . 2
5 Apparatus . 3
6 Procedure . 3
6.1 Blank titration. 3
6.2 Washing of the surface . 3
6.3 Wash-water titration . 4
7 Expression of results . 4
8 Test report . 5
Bibliography . 6

ISO 8502-2:2005(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 8502-2 was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee SC 12,
Preparation of steel substrates before application of paints and related products.
This second edition cancels and replaces the first edition (ISO 8502-2:1992), which has been technically
revised.
ISO 8502 consists of the following parts, under the general title Preparation of steel substrates before
application of paints and related products — Tests for the assessment of surface cleanliness:
 Part 1: Field test for soluble iron corrosion products (withdrawn) [Technical Report]
 Part 2: Laboratory determination of chloride on cleaned surfaces
 Part 3: Assessment of dust on steel surfaces prepared for painting (pressure-sensitive tape method)
 Part 4: Guidance on the estimation of the probability of condensation prior to paint application
 Part 5: Measurement of chloride on steel surfaces prepared for painting (ion detection tube method)
 Part 6: Extraction of soluble contaminants for analysis — The Bresle method
 Part 8: Field method for the refractometric determination of moisture
 Part 9: Field method for the conductometric determination of water-soluble salts
 Part 10: Field method for the titrimetric determination of water-soluble chloride (withdrawn)
 Part 11: Field method for the turbidimetric determination of water-soluble sulfate
 Part 12: Field method for the titrimetric determination of water-soluble ferrous ions
This corrected version of ISO 8502-2:2005 incorporates the following corrections:
 in 4.5 “0,012 5 mg/l” has been changed to “0,012 5 mol/l”;
−5 −2
 in 4.5.2 the numerator in the equation has been changed from “2,8 × 10 ” to “2,8 × 10 ” and the
volume unit has been added in the where clause, giving “V is the volume, in millilitres, of the
mercury(II) nitrate solution consumed.”
iv © ISO 2005 – All rights reserved

ISO 8502-2:2005(E)
Introduction
The performance of protective coatings of paint and related products applied to steel is significantly affected
by the state of the steel surface immediately prior to painting. The principal factors that are known to influence
this performance are
a) the presence of rust and mill scale,
b) the presence of surface contaminants, including salts, dust, oils and greases, and
c) the surface profile.
ISO 8501, ISO 8502 and ISO 8503 have been prepared to provide methods of assessing these factors, while
ISO 8504 provides guidance on the preparation methods that are available for cleaning steel substrates,
indicating the capabilities of each in attaining specified levels of cleanliness.
These International Standards do not contain recommendations for the protective coating systems to be
applied to the steel surface. Neither do they contain recommendations for the surface quality requ
...