EN 15410:2011

EN 15410:2011 is a standard published by the European Committee for Standardization (CEN). Its full title is "Solid recovered fuels - Methods for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti)". This standard covers: This European Standard specifies three methods of digestion for solid recovered fuels: a) microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture; b) hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample; c) oven digestion with nitric, perchloric and hydrofluoric acid mixture. Instrumental determination of Si, Al, K, Na, Ca, Mg, Fe, P, and Ti is performed by Inductively Coupled Plasma Spectrometry with optical detection or other suitable spectroscopic techniques such as Flame Atomic Spectroscopy. The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary an alternative digestion method (among those proposed) shall be used. XRF can be used for the analysis of Si, Al, K, Na, Ca, Mg, Fe, P, Ti, after ashing (550 °C) of the sample: other elements can be analysed by XRF provided that the concentration levels are above the instrumental detection limits of the XRF instrumentation and after proper preliminary testing. Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter. Method b) is recommended for SRFs with high organic matter concentration that can be difficult to digest with the other methods. Method c) is recommended for SRFs samples for which the other methods leave a significant insoluble residue. All the listed methods are suitable for the determination of Si, provided that closed containers are used for sample dissolution. XRF is highly recommended for Si, P and Ti analysis. Alternative digestion methods can be applied if their performance is proved to be comparable with those of the methods mentioned in a) to c) (see Annex C).

This European Standard specifies three methods of digestion for solid recovered fuels: a) microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture; b) hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample; c) oven digestion with nitric, perchloric and hydrofluoric acid mixture. Instrumental determination of Si, Al, K, Na, Ca, Mg, Fe, P, and Ti is performed by Inductively Coupled Plasma Spectrometry with optical detection or other suitable spectroscopic techniques such as Flame Atomic Spectroscopy. The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary an alternative digestion method (among those proposed) shall be used. XRF can be used for the analysis of Si, Al, K, Na, Ca, Mg, Fe, P, Ti, after ashing (550 °C) of the sample: other elements can be analysed by XRF provided that the concentration levels are above the instrumental detection limits of the XRF instrumentation and after proper preliminary testing. Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter. Method b) is recommended for SRFs with high organic matter concentration that can be difficult to digest with the other methods. Method c) is recommended for SRFs samples for which the other methods leave a significant insoluble residue. All the listed methods are suitable for the determination of Si, provided that closed containers are used for sample dissolution. XRF is highly recommended for Si, P and Ti analysis. Alternative digestion methods can be applied if their performance is proved to be comparable with those of the methods mentioned in a) to c) (see Annex C).

EN 15410:2011 is classified under the following ICS (International Classification for Standards) categories: 75.160.10 - Solid fuels; 75.160.40 - Biofuels. The ICS classification helps identify the subject area and facilitates finding related standards.

EN 15410:2011 has the following relationships with other standards: It is inter standard links to CEN/TS 15410:2006, EN ISO 3884:2025, ISO 9964-1:1993, ISO 9964-2:1993, ISO 9964-3:1993, EN 13656:2020, EN ISO 21660-3:2021, EN 29048:1990, EN ISO 15586:2003, EN 28394:1990, EN ISO 21656:2021, EN ISO 12020:2000, EN 15357:2011, EN ISO 3696:1995, EN ISO 11885:2009. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

EN 15410:2011 is associated with the following European legislation: Standardization Mandates: M/325. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.

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