EN ISO 22744-1:2020

SLOVENSKI STANDARD
01-september-2020
Tekstilije in tekstilni izdelki - Določevanje organokositrnih spojin - 1. del: Metoda
derivatizacije s plinsko kromatografijo (ISO 22744-1:2020)
Textiles and textile products - Determination of organotin compounds - Part 1:
Derivatisation method using gas chromatography (ISO 22744-1:2020)
Textilien und textile Erzeugnisse - Bestimmung von zinnorganischen Verbindungen - Teil
1: Derivatisierung für das gaschromatische Verfahren (ISO 22744-1:2020)
Textiles et produits textiles - Détermination des composés organostanniques - Partie 1:
Méthode de dérivation utilisant la chromatographie en phase (ISO 22744-1:2020)
Ta slovenski standard je istoveten z: EN ISO 22744-1:2020
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 22744-1
EUROPEAN STANDARD
NORME EUROPÉENNE
June 2020
EUROPÄISCHE NORM
ICS 59.080.01
English Version
Textiles and textile products - Determination of organotin
compounds - Part 1: Derivatisation method using gas
chromatography (ISO 22744-1:2020)
Textiles et produits textiles - Détermination des Textilien und textile Erzeugnisse - Bestimmung von
composés organostanniques - Partie 1: Méthode de zinnorganischen Verbindungen - Teil 1:
dérivation utilisant la chromatographie en phase (ISO Derivatisierung für das gaschromatische Verfahren
22744-1:2020) (ISO 22744-1:2020)
This European Standard was approved by CEN on 24 April 2020.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 22744-1:2020 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 22744-1:2020) has been prepared by Technical Committee ISO/TC 38
"Textiles" in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the
secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by December 2020, and conflicting national standards
shall be withdrawn at the latest by December 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 22744-1:2020 has been approved by CEN as EN ISO 22744-1:2020 without any
modification.
INTERNATIONAL ISO
STANDARD 22744-1
First edition
2020-05
Textiles and textile products —
Determination of organotin
compounds —
Part 1:
Derivatisation method using gas
chromatography
Textiles et produits textiles — Détermination des composés
organostanniques —
Partie 1: Méthode de dérivation utilisant la chromatographie en
phase gazeuse
Reference number
ISO 22744-1:2020(E)
©
ISO 2020
ISO 22744-1:2020(E)
© ISO 2020
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
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Published in Switzerland
ii © ISO 2020 – All rights reserved

ISO 22744-1:2020(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 2
6 Apparatus and materials. 3
7 Preparation of the test piece . 3
8 Procedure. 4
8.1 General . 4
8.2 Preparation of the sodium tetraethylborate solution. 4
8.3 Preparation of standard solutions . 4
8.3.1 General. 4
8.3.2 Internal standards — Stock solution (100 mg/l of organotin cation) . 5
8.3.3 Internal standards — Working solution (10 mg/l of organotin cation) . 5
8.3.4 Target compounds — Stock solution (1 000 mg/l of organotin cation) . 6
8.3.5 Target compounds — Working solution (10 mg/l of organotin cation) . 6
8.4 Preparation of the tropolone solution . 6
8.5 Preparation of the buffer solution . 6
8.6 Preparation of the calibration solutions . 6
8.7 Sample preparation . 7
8.8 Preparation of the blank solution . 7
8.9 Gas chromatography . 7
9 Expression of results . 8
10 Test report .10
Annex A (informative) Suggested gas chromatography-mass spectrometry (GC-MS)
conditions for organotin analysis .11
Annex B (informative) Reliability of the method .12
Bibliography .13
ISO 22744-1:2020(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso .org/
iso/ foreword .html.
This document was prepared by the European Committee for Standardization (CEN) Technical
Committee CEN/TC 248, Textiles and textile products, in collaboration with ISO Technical Committee
ISO/TC 38, Textiles, in accordance with the Agreement on technical cooperation between ISO and CEN
(Vienna Agreement).
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
iv © ISO 2020 – All rights reserved

INTERNATIONAL STANDARD ISO 22744-1:2020(E)
Textiles and textile products — Determination of organotin
compounds —
Part 1:
Derivatisation method using gas chromatography
WARNING — The use of this document involves hazardous materials. It does not purport
to address all of the safety or environmental problems associated with its use. It is the
responsibility of users of this document to take appropriate measures to ensure the safety and
health of personnel and the environment prior to application of the document.
1 Scope
This document specifies a test method for the qualification and quantification of organotin compounds.
This test method is applicable to all types of materials of textile products.
NOTE CEN/TR 16741 defines which materials are applicable to this determination.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 3696, Water for analytical laboratory use — Specification and test methods
ISO 4787, Laboratory glassware — Volumetric instruments — Methods for testing of capacity and for use
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
4 Principle
The organotin substances are extracted from the material of a textile product with a methanol-ethanol
mixture using tropolone as a complexing agent.
The polar and high-boiling organotin is then converted to the corresponding volatile alkyl derivative,
by reaction with sodium tetraethylborate, NaB(Et) . Finally, it is detected and quantified by using a gas
chromatograph fitted with a mass selective detector (GC-MS).
Table 1 indicates the list of target compounds which can be analysed with this document.
This document is also applicable for further organotin substances provided that the method is validated
with the additional compounds.
ISO 22744-1:2020(E)
Table 1 — List of target compounds that can be analysed and internal standards
Type of
a
Compound CAS number
compound
Internal standard: n-Heptyltin trichloride 59344–47–7
Methyltin trichloride 993–16–8
Monosubstituted n-Butyltin trichloride 1118–46–3
n-Octyltin trichloride 3091–25–6
Phenyltin trichloride 1124–19–2
Internal standard: Di-n-heptyltin dichloride 74340–12–8
Dimethyltin dichloride 753–73–1
Di-n-propyltin dichloride 867–36–7
Disubstituted
Di-n-butyltin dichloride 683–18–1
Di-n-octyltin dichloride 3542–36–7
Diphenyltin dichloride 1135–99–5
Internal standard: Tri-n-pentyltin chloride 3342–67–4
Trimethyltin chloride 1066–45–1
Tri-n-propyltin chloride 2279–76–7
b
Trisubstituted Tri-n-butyltin chloride 1461–22–9
Tri-n-octyltin chloride 2587–76–0
Triphenyltin chloride (or fentin chloride) 639–58–7
Tricyclohexyltin chloride 3091–32–5
Internal standard: Tetra-n-propyltin 2176–98–9
Tetrasubstituted Tetra-n-ethyltin 597–64–8
Tetra-n-butyltin 1461–25–2
a
Chemical Abstract Service.
b
If bis(tri-n-butyltin)oxide (TBTO), CAS number 56–35–9, is present, it is detected as tri-
n-butyltin.
5 Reagents
Unless otherwise specified, use only reagents of recognized analytical grade.
5.1 Water, grade 3 according to ISO 3696.
5.2 Ethanol, technical grade or industrial methylated spirit (IMS), CAS number: 64-17-5.
5.3 Glacial acetic acid, CAS number: 64-19-7.
5.4 Sodium tetraethylborate, CAS number: 15523-24-7.
5.5 Tetrahydrofuran (THF), stabilized, CAS number: 109-99-9.
5.6 n-Heptyltin trichloride, CAS number: 59344-47-7 (internal standard).
5.7 Di-n-heptyltin dichloride, CAS number: 74340-12-8 (internal standard).
5.8 Tri-n-pentyltin chloride, CAS number: 3342-67-4 (internal standard).
2 © ISO 2020 – All rights reserved

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