EN 16136:2011
(Main)Automotive fuels - Determination of manganese content in unleaded petrol - Inductively coupled plasma optical emission spectrometry (ICP OES) method
General Information
- Abstract
This European Standard specifies a method based on inductively coupled plasma optical emission spectrometry (ICP OES) for the determination of manganese content as methylcyclopentadienyl manganese tricarbonyl (MMT )) in unleaded petrol from about 2 mg/l to about 8 mg/l. This test method is applicable to unleaded petrol containing up to 3,7 % (m/m) oxygen, including those with ethanol up to 10 % (V/V).
NOTE 1 Manganese as MMT is added to petrol to increase anti-knock properties.
WARNING - The use of this European Standard may involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this European Standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.
NOTE 2 Solutions of MMT in petrol are unstable when exposed to light. Low and erratic results are expected if petrol samples are exposed to light prior the analysis.
NOTE 3 Manganese contents higher than 8 mg/l can be measured after preliminary dilution of the sample with a suitable solvent. However, the precision has not been established for such a procedure.
NOTE 4 Application of the test method to the determination of other manganese compounds in petrol has not been tested.
NOTE 5 For the purposes of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction (µ) and the volume fraction of a material respectively.
- Status
- Withdrawn
- Publication Date
- 06-Dec-2011
- Withdrawal Date
- 22-Sep-2026
- Technical Committee
- CEN/TC 19 - Petroleum products, lubricants and related products
- Drafting Committee
- CEN/TC 19/WG 27 - Elemental analysis of petroleum and related products
- Current Stage
- 9960 - Withdrawal effective - Withdrawal
- Start Date
- 11-Feb-2015
- Completion Date
- 23-Sep-2026
Relations
- Effective Date
- 18-Feb-2015
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
- Effective Date
- 28-Jan-2026
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Frequently Asked Questions
EN 16136:2011 is a standard published by the European Committee for Standardization (CEN). Its full title is "Automotive fuels - Determination of manganese content in unleaded petrol - Inductively coupled plasma optical emission spectrometry (ICP OES) method". This standard covers: This European Standard specifies a method based on inductively coupled plasma optical emission spectrometry (ICP OES) for the determination of manganese content as methylcyclopentadienyl manganese tricarbonyl (MMT )) in unleaded petrol from about 2 mg/l to about 8 mg/l. This test method is applicable to unleaded petrol containing up to 3,7 % (m/m) oxygen, including those with ethanol up to 10 % (V/V). NOTE 1 Manganese as MMT is added to petrol to increase anti-knock properties. WARNING - The use of this European Standard may involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this European Standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use. NOTE 2 Solutions of MMT in petrol are unstable when exposed to light. Low and erratic results are expected if petrol samples are exposed to light prior the analysis. NOTE 3 Manganese contents higher than 8 mg/l can be measured after preliminary dilution of the sample with a suitable solvent. However, the precision has not been established for such a procedure. NOTE 4 Application of the test method to the determination of other manganese compounds in petrol has not been tested. NOTE 5 For the purposes of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction (µ) and the volume fraction of a material respectively.
This European Standard specifies a method based on inductively coupled plasma optical emission spectrometry (ICP OES) for the determination of manganese content as methylcyclopentadienyl manganese tricarbonyl (MMT )) in unleaded petrol from about 2 mg/l to about 8 mg/l. This test method is applicable to unleaded petrol containing up to 3,7 % (m/m) oxygen, including those with ethanol up to 10 % (V/V). NOTE 1 Manganese as MMT is added to petrol to increase anti-knock properties. WARNING - The use of this European Standard may involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this European Standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use. NOTE 2 Solutions of MMT in petrol are unstable when exposed to light. Low and erratic results are expected if petrol samples are exposed to light prior the analysis. NOTE 3 Manganese contents higher than 8 mg/l can be measured after preliminary dilution of the sample with a suitable solvent. However, the precision has not been established for such a procedure. NOTE 4 Application of the test method to the determination of other manganese compounds in petrol has not been tested. NOTE 5 For the purposes of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction (µ) and the volume fraction of a material respectively.
EN 16136:2011 is classified under the following ICS (International Classification for Standards) categories: 75.160.20 - Liquid fuels. The ICS classification helps identify the subject area and facilitates finding related standards.
EN 16136:2011 has the following relationships with other standards: It is inter standard links to EN 16136:2015, EN ISO 3171:1999, EN ISO 1042:1999, EN ISO 12185:2024, EN ISO 3675:1998, EN ISO 3170:2025, EN 228:2012. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
EN 16136:2011 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.RUQHPVNORSOMHQRKraftstoffe für Kraftfahrzeuge - Bestimmung des Mangangehalts in unverbleitem Ottokraftstoff - Optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES)Carburants pour automobiles - Détermination de la teneur en manganèse dans les essences sans plomb - Méthode d'émission atomique à couplage inductif par plasma (ICP OES)Automotive fuels - Determination of manganese content in unleaded petrol - Inductively coupled plasma optical emission spectrometry (ICP OES) method75.160.20Liquid fuelsICS:Ta slovenski standard je istoveten z:EN 16136:2011SIST EN 16136:2012en,fr,de01-februar-2012SIST EN 16136:2012SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16136
December 2011 ICS 75.160.20 English Version
Automotive fuels - Determination of manganese content in unleaded petrol - Inductively coupled plasma optical emission spectrometry (ICP OES) method
Carburants pour automobiles - Détermination de la teneur en manganèse dans les essences sans plomb - Méthode spectrométrique optique par plasma à couplage inductif (ICP OES)
Kraftstoffe für Kraftfahrzeuge - Bestimmung des Mangangehalts in unverbleitem Ottokraftstoff - Optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES) This European Standard was approved by CEN on 29 October 2011.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2011 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16136:2011: ESIST EN 16136:2012
1) MMT is a registered trademark of Ethyl Corporation. SIST EN 16136:2012
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