General Information

Abstract

This European Standard specifies three methods of digestion for solid recovered fuels:
a) microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture;
b) hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs
sample;
c) oven digestion with nitric, perchloric and hydrofluoric acid mixture.
Instrumental determination of As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Mo, Ni, Sb, Se, Tl, V, Zn is performed by
Inductively Coupled Plasma with optical or mass detection or graphite furnace Atomic Absorption
Spectrometry. Hg can be analysed only after the microwave assisted procedure or, alternatively, by a direct
analysis method (Hg direct  AMA).
The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the
remaining residue. If necessary, an alternative digestion method (among those proposed) is used.
Method a) is recommended for general use, but the amount of the test portion can be very low in case of high
concentration of organic matter.
Method b) is recommended for Solid Recovered Fuel (SRF) with high organic matter concentration that can
be difficult to digest with the other methods. This method is not suitable for mercury.
Method c) is recommended for Solid Recovered Fuel (SRF) samples for which the other methods leave a
significant insoluble residue.
Alternative digestion methods can be applied if their performance is proved to be comparable with those of the
methods mentioned in a) to c) (see Annex C).

Status
Withdrawn
Publication Date
06-Sep-2011
Withdrawal Date
22-Sep-2026
Current Stage
9960 - Withdrawal effective - Withdrawal
Start Date
23-Apr-2025
Completion Date
23-Sep-2026

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Effective Date
10-Sep-2011
Effective Date
21-Dec-2022
Effective Date
28-Jan-2026
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28-Jan-2026
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28-Jan-2026
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28-Jan-2026
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28-Jan-2026
Effective Date
28-Jan-2026

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Frequently Asked Questions

EN 15411:2011 is a standard published by the European Committee for Standardization (CEN). Its full title is "Solid recovered fuels - Methods for the determination of the content of trace elements (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn)". This standard covers: This European Standard specifies three methods of digestion for solid recovered fuels: a) microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture; b) hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample; c) oven digestion with nitric, perchloric and hydrofluoric acid mixture. Instrumental determination of As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Mo, Ni, Sb, Se, Tl, V, Zn is performed by Inductively Coupled Plasma with optical or mass detection or graphite furnace Atomic Absorption Spectrometry. Hg can be analysed only after the microwave assisted procedure or, alternatively, by a direct analysis method (Hg direct AMA). The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary, an alternative digestion method (among those proposed) is used. Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter. Method b) is recommended for Solid Recovered Fuel (SRF) with high organic matter concentration that can be difficult to digest with the other methods. This method is not suitable for mercury. Method c) is recommended for Solid Recovered Fuel (SRF) samples for which the other methods leave a significant insoluble residue. Alternative digestion methods can be applied if their performance is proved to be comparable with those of the methods mentioned in a) to c) (see Annex C).

This European Standard specifies three methods of digestion for solid recovered fuels: a) microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture; b) hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample; c) oven digestion with nitric, perchloric and hydrofluoric acid mixture. Instrumental determination of As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Mo, Ni, Sb, Se, Tl, V, Zn is performed by Inductively Coupled Plasma with optical or mass detection or graphite furnace Atomic Absorption Spectrometry. Hg can be analysed only after the microwave assisted procedure or, alternatively, by a direct analysis method (Hg direct AMA). The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary, an alternative digestion method (among those proposed) is used. Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter. Method b) is recommended for Solid Recovered Fuel (SRF) with high organic matter concentration that can be difficult to digest with the other methods. This method is not suitable for mercury. Method c) is recommended for Solid Recovered Fuel (SRF) samples for which the other methods leave a significant insoluble residue. Alternative digestion methods can be applied if their performance is proved to be comparable with those of the methods mentioned in a) to c) (see Annex C).

EN 15411:2011 is classified under the following ICS (International Classification for Standards) categories: 75.160.10 - Solid fuels; 75.160.40 - Biofuels. The ICS classification helps identify the subject area and facilitates finding related standards.

EN 15411:2011 has the following relationships with other standards: It is inter standard links to CEN/TS 15411:2006, EN ISO 3884:2025, EN 13656:2020, EN ISO 21660-3:2021, EN 15357:2011, EN ISO 3696:1995, EN ISO 21656:2021, EN ISO 12952-1:2010, EN 1102:2016, EN ISO 12952-2:2010, EN ISO 3759:2011, EN ISO 3175-1:2018. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

EN 15411:2011 is associated with the following European legislation: Standardization Mandates: M/325. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.

EN 15411:2011 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Feste Sekundärbrennstoffe - Verfahren zur Bestimmung des Gehaltes an Spurelementen (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn)Combustibles solides de récupération - Méthodes de détermination de la teneur en éléments à l'état de traces (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V et Zn)Solid recovered fuels - Methods for the determination of the content of trace elements (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn)75.160.10Trda gorivaSolid fuelsICS:Ta slovenski standard je istoveten z:EN 15411:2011SIST EN 15411:2011en,de01-november-2011SIST EN 15411:2011SLOVENSKI
STANDARDSIST-TS CEN/TS 15411:20071DGRPHãþD

EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 15411
September 2011 ICS 75.160.10 Supersedes CEN/TS 15411:2006English Version
Solid recovered fuels - Methods for the determination of the content of trace elements (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn)
Combustibles solides de récupération - Méthodes de détermination de la teneur en éléments à l'état de traces (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V et Zn)
Feste Sekundärbrennstoffe - Verfahren zur Bestimmung des Gehaltes an Spurelementen (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V und Zn) This European Standard was approved by CEN on 15 July 2011.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2011 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15411:2011: ESIST EN 15411:2011

Guidelines - Characteristics of the laboratory sample for chemical analysis of SRF . 11Annex B (informative)
Performance data . 13Annex C (informative)
Major results of ruggedness testing . 22Bibliography . 25 SIST EN 15411:2011

1,14 g/ml. 7.4 Perchloric acid (HClO4), 70 % (w/w), ρ
1,62 g/ml. 7.5 Hydrochloric acid (HCl), 65 % (w/w), ρ
1,40 g/ml. 8 Procedure 8.1 Sample conservation and pre-treatment The laboratory samples shall be stored according to guidelines defined in Annex A. SIST EN 15411:2011

EN ISO 17294-2, GF-AAS and CV-AAS/HG-AAS (Cold Vapour and Hydride Generation Atomic Absorption) according to the principle of the method reported in ASTM E885-88 or direct mercury analysis according to the method reported in EPA Method 7473.
Instruments shall be set up and calibrated following the manufacturers' instructions and the used reference methods. 11 Expression of results The results are expressed in milligram per kilogram on a dry basis. For procedure B on SRF ash, the following equation shall be used to express the results on dry original matter: 100ashashdACC×= where Cd
is concentration on dry basis in the original sample; Cash is concentration in the ash; Aash is ash content (%). 12 Quality control To detect possible contaminations from vessels and/or reagents, blank tests shall be carried out by the same sample preparation procedure, using the same quantities of reagents. SIST EN 15411:2011
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